Under emergency circumstances, dangerous goods transport is affected, and the consequences are fatal. Therefore, the robustness of hazardous goods transportation network is analyzed for facilitating the design of that network. In this paper, based on natural seepage phenomenon and the percolation theory of complex networks, the robustness of dangerous goods transportation network is defined, and then, from the perspective of wholeness, network connectivity rate is proposed based on graph theory. From the perspective of micro details, they are put forward that the number of percolation nodes, the failure rate of percolation, node capacity, and the percolation damping parameter. Starting from these definitions and the actuality, models are established and the simulation scenario with assumptions is set up. Finally, according to the simulation flow chart, Matlab simulation is adopted. According to the simulation results, we apply qualitative and quantitative analysis to acquiring the influence of the percolation robustness of hazardous goods transportation network for nodes failure with the different node- degree and node- capacity coefficient in emergency conditions.